What is the concentration of #"AlF"_6^"3-"# after mixing #"25 cm"^3# of 0.1 mol/L aluminium ion with #"25 cm"^3# of 1 mol/L fluoride ion?

For #"AlF"_6^"3-", K_text(eq) = 1.0 × 10^25#

Answer 1

I get #["AlF"_6^"3-"] ="0.0050 mol/dm"^3#.

The balance is

#"Al"^"3+" + "6F"^"-" ⇌ "AlF"_6^(3-)#
#K_"eq" = 1.0 × 10^25#.

This implies that the response will essentially proceed to its conclusion.

This turns into a problem with limiting reactants.

#"Moles of Al"^(3+) = 0.025 color(red)(cancel(color(black)("dm"^3 "Al"^(3+)))) × ("0.010 mol Al"^(3+))/(1 color(red)(cancel(color(black)("dm"^3 "Al"^(3+))))) = "0.000 25 mol Al"^"3+"#
#"Moles of AlF"_6^"3-" color(white)(l)"from Al"^(3+) = "0.000 25" color(red)(cancel(color(black)("mol Al"^(3+)))) × ("1 mol AlF"_6^"3-")/(1 color(red)(cancel(color(black)("mol Al"^(3+))))) = "0.000 25 mol AlF"_6^"3-"#
#"Moles of F"^"-" = 0.025 color(red)(cancel(color(black)("dm"^3 "F"^"-"))) × ("0.10 mol F"^"-")/(1 color(red)(cancel(color(black)("dm"^3 "F"^"-")))) = "0.0025 mol F"^"-"#
#"Moles of AlF"_6^"3-" color(white)(l)"from F"^"-" = 0.0025 color(red)(cancel(color(black)("mol F"^"-"))) × ("1 mol AlF"_6^"3-")/(6 color(red)(cancel(color(black)("mol F"^"-")))) = "0.000 433 mol AlF"_6^(3-)#
#"Al"^(3+)# gives the fewest moles of #"AlF"_6^"3-"#, so #"Al"^(3+)# is the limiting reactant.
Thus, when the reaction is complete, we have #"0.000 25 mol AlF"_6^"3-"# in #"50 cm"^3# of solution.
∴ #["AlF"_6^"3-"] ="0.000 25 mol"/("0.050 dm"^3) = "0.0050 mol/dm"^3#
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Answer 2

To find the concentration of AlF63\text{AlF}_6^{3-} after mixing, we need to consider the reaction between aluminum ion (Al3+\text{Al}^{3+}) and fluoride ion (F\text{F}^-). The balanced chemical equation for the reaction is:

Al3++6FAlF63\text{Al}^{3+} + 6\text{F}^- \rightarrow \text{AlF}_6^{3-}

Given the volumes and concentrations of the ions, we can use the formula for dilution to find the final concentration:

C1V1=C2V2C_1V_1 = C_2V_2

where C1C_1 and V1V_1 are the initial concentration and volume of the aluminum ion, and C2C_2 and V2V_2 are the final concentration and volume after mixing.

Substitute the given values:

(0.1mol/L)×(25cm3)=C2×(25cm3+25cm3)(0.1 \, \text{mol/L}) \times (25 \, \text{cm}^3) = C_2 \times (25 \, \text{cm}^3 + 25 \, \text{cm}^3)

(0.1mol/L)×(25cm3)=C2×(50cm3)(0.1 \, \text{mol/L}) \times (25 \, \text{cm}^3) = C_2 \times (50 \, \text{cm}^3)

C2=(0.1mol/L)×(25cm3)50cm3C_2 = \frac{(0.1 \, \text{mol/L}) \times (25 \, \text{cm}^3)}{50 \, \text{cm}^3}

C2=0.05mol/LC_2 = 0.05 \, \text{mol/L}

So, the concentration of AlF63\text{AlF}_6^{3-} after mixing is 0.05mol/L0.05 \, \text{mol/L}.

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Answer from HIX Tutor

When evaluating a one-sided limit, you need to be careful when a quantity is approaching zero since its sign is different depending on which way it is approaching zero from. Let us look at some examples.

When evaluating a one-sided limit, you need to be careful when a quantity is approaching zero since its sign is different depending on which way it is approaching zero from. Let us look at some examples.

When evaluating a one-sided limit, you need to be careful when a quantity is approaching zero since its sign is different depending on which way it is approaching zero from. Let us look at some examples.

When evaluating a one-sided limit, you need to be careful when a quantity is approaching zero since its sign is different depending on which way it is approaching zero from. Let us look at some examples.

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