Why does gibbs free energy decrease with temperature?

Answer 1

For a given reaction, an increase in temperature can result in a change in either the free energy (G) or the entropy (S) change.

Since I am unable to type the Greek letter, I will substitute "d" for it. The equation for the change in free energy is dG = dH - TdS, where H is the enthalpy, S is the entropy, and T is the Kelvin temperature. Since the change in G depends on minus T times the change in S, if the entropy decreases (i.e., dS is negative), then -TdS is positive. As a result, as the temperature rises, the free energy value increases.

In contrast, when entropy increases, dS will be positive and -TdS will become more negative as temperature rises, resulting in a decrease in the free energy's numerical value.

A reaction with a delta G of -2000 kJ yields more free energy than one with a delta G of -1000 kJ, but -1000 is a bigger number than -2000, so you have to be careful with the terminology!

Sign up to view the whole answer

By signing up, you agree to our Terms of Service and Privacy Policy

Sign up with email
Answer 2

The Gibbs free energy decreases with temperature because the entropy term (TΔS) becomes more dominant, outweighing the enthalpy term (ΔH).

Sign up to view the whole answer

By signing up, you agree to our Terms of Service and Privacy Policy

Sign up with email
Answer from HIX Tutor

When evaluating a one-sided limit, you need to be careful when a quantity is approaching zero since its sign is different depending on which way it is approaching zero from. Let us look at some examples.

When evaluating a one-sided limit, you need to be careful when a quantity is approaching zero since its sign is different depending on which way it is approaching zero from. Let us look at some examples.

When evaluating a one-sided limit, you need to be careful when a quantity is approaching zero since its sign is different depending on which way it is approaching zero from. Let us look at some examples.

When evaluating a one-sided limit, you need to be careful when a quantity is approaching zero since its sign is different depending on which way it is approaching zero from. Let us look at some examples.

Not the question you need?

Drag image here or click to upload

Or press Ctrl + V to paste
Answer Background
HIX Tutor
Solve ANY homework problem with a smart AI
  • 98% accuracy study help
  • Covers math, physics, chemistry, biology, and more
  • Step-by-step, in-depth guides
  • Readily available 24/7