Predict the expected pH at the endpoint of the titration of weak acid and a strong base? Maleic Acid and NaOH?

Answer 1

The question is a bit ambiguous.........I would answer #(c)#, and I may be wrong........

Maleic acid reacts with #"TWO equiv"# of sodium hydroxide......
#"HO"_2"CCH=CHCO"_2"H(aq)" + "2NaOH(aq)"rarr""^(-)"O"_2"CCH=CHCO"_2^(-)"Na"_2^+#
Because it is a DIACID that requires 2 equiv of NaOH, at the endpoint we predict that we have a solution that is stoichiometric in #""^(-)"O"_2"CCH=CHCO"_2^(-)"Na"_2^+#. And we would expect this species to act as a WEAK base in water.......i.e.
#""^(-)"O"_2"CCH=CHCO"_2^(-)"Na"_2^+ + H_2O rightleftharpoons "HO"_2"CCH=CHCO"_2^(-)"Na"^+ + "NaOH(aq)"#
Are you following me? I know I am being a little bit abstract in suggesting that the diacid gets robbed of its two protons to form the dicarboxylate, and then itself robs the water of one proton to give equilibrium quantities of #"HO"_2"CCH=CHCO"_2^(-)"Na"^+# (of course this association reaction will not be quantitative).

We could work out this reaction quantitatively, but I am going to have my breakfast first.......

Sign up to view the whole answer

By signing up, you agree to our Terms of Service and Privacy Policy

Sign up with email
Answer 2

1st equivalence point: (a) pH < 7 ; 2nd equivalence point: (c) pH > 7.

The question is worded ambiguously because maleic acid is a dibasic acid.

#"H"_2"A" + "H"_2"O" ⇌ "H"_3"O"^"+" + "HA"^"-"; "p"K_text(a1) = 1.9"#
#"HA"^"-" + "H"_2"O" ⇌ "H"_3"O"^"+" + "A"^"2-"; color(white)(ll)"p"K_text(a2) = 6.07"#

Thus, there are two equivalence points: one for the removal of the first proton and one for the second, similar to the titration curve below.

pH at 1st equivalence point

A common formula for the pH at the first equivalence point of a dibasic acid is

#color(blue)(bar(ul(|color(white)(a/a)"pH" = ("p"K_text(a1) + "p"K_text(a2))/2color(white)(a/a)|)))" "#

#"pH" = (1.9 + 6.07)/2 = 3.98#

pH at 2nd equivalence point

At this point, we have a solution of #"A"^"2-"#.

The equilibrium is

#"A"^"2-" + "H"_2"O" ⇌ "HA"^"-" + "OH"^"-"#

The conjugate base of a weak acid is a base, so the pH will be greater than 7, probably around pH 9.

Sign up to view the whole answer

By signing up, you agree to our Terms of Service and Privacy Policy

Sign up with email
Answer 3

The expected pH at the endpoint of the titration of a weak acid and a strong base depends on the specific weak acid and strong base being used, as well as their concentrations. For maleic acid (a weak acid) and NaOH (a strong base) titration, the pH at the endpoint will be slightly above 7, typically around 8-10, because the strong base (NaOH) will neutralize the weak acid (maleic acid) to form its conjugate base (the sodium salt of maleic acid) and water.

Sign up to view the whole answer

By signing up, you agree to our Terms of Service and Privacy Policy

Sign up with email
Answer from HIX Tutor

When evaluating a one-sided limit, you need to be careful when a quantity is approaching zero since its sign is different depending on which way it is approaching zero from. Let us look at some examples.

When evaluating a one-sided limit, you need to be careful when a quantity is approaching zero since its sign is different depending on which way it is approaching zero from. Let us look at some examples.

When evaluating a one-sided limit, you need to be careful when a quantity is approaching zero since its sign is different depending on which way it is approaching zero from. Let us look at some examples.

When evaluating a one-sided limit, you need to be careful when a quantity is approaching zero since its sign is different depending on which way it is approaching zero from. Let us look at some examples.

Not the question you need?

Drag image here or click to upload

Or press Ctrl + V to paste
Answer Background
HIX Tutor
Solve ANY homework problem with a smart AI
  • 98% accuracy study help
  • Covers math, physics, chemistry, biology, and more
  • Step-by-step, in-depth guides
  • Readily available 24/7