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How does electronegativity change across a period?

Answer 1

Would it not increase due to increasing #Z_"the atomic number"#, i.e. increasing nucular charge?

As always, electronegativity, the tendency of an atom involved in a chemical bond to polarize electron density towards itself, is a function of (i) nuclear charge, and (ii) shielding by other electrons. Incomplete electronic shells shield the nuclear charge VERY ineffectively with the result that electronegativity increases ACROSS the Period from LEFT to RIGHT as we face the Table, but DECREASES down the Group.

And as chemists, as scientists, we should look at some data...even tho electronegativity is a bit of a contrived measurement...the scales have been normalized to give values between #0# and #4#.

Are these values roughly consistent with what we have argued? The electronegativity of fluorine at #4.0# contrasts with that of lithium at #1.0#, and that of astatine at #2.2#...

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Answer 2

Brooklyn Barber

Electronegativity generally increases across a period from left to right.

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Answer from HIX Tutor

When evaluating a one-sided limit, you need to be careful when a quantity is approaching zero since its sign is different depending on which way it is approaching zero from. Let us look at some examples.