How do you calculate the standard enthalpy of reaction, #DeltaH_(rxn)^@# for the following reaction from the given standard heats formation (#DeltaH_f^@#) values: #4NH_3(g) + 5O_2(g) -> 4NO(g) + 6H_2O(g)#?

Answer 1

#DeltaH_"rxn"^@=DeltaH_f^@("products")-DeltaH_f^@("reactants")#

And here, #DeltaH_"rxn"^@=..................#
#(4xx90.3-6xx241.8-{4xx-45.9})*kJ*mol^-1#
#=-906*kJ*mol^-1#.

The formation of water clearly dominates the enthalpy change, it is a thermodynamic sink.

ANd of course, #DeltaH_f^@=0# for an element (here dixoygen) in its standard state (they even spoon-feed you this fact).
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Answer 2

[ \Delta H_{\text{rxn}}^{\circ} = \sum (\Delta H_{f}^{\circ} \text{ of products}) - \sum (\Delta H_{f}^{\circ} \text{ of reactants}) ]

[ \Delta H_{\text{rxn}}^{\circ} = [4 \Delta H_{f}^{\circ}(\text{NO}) + 6 \Delta H_{f}^{\circ}(\text{H}2\text{O})] - [4 \Delta H{f}^{\circ}(\text{NH}3) + 5 \Delta H{f}^{\circ}(\text{O}_2)] ]

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Answer from HIX Tutor

When evaluating a one-sided limit, you need to be careful when a quantity is approaching zero since its sign is different depending on which way it is approaching zero from. Let us look at some examples.

When evaluating a one-sided limit, you need to be careful when a quantity is approaching zero since its sign is different depending on which way it is approaching zero from. Let us look at some examples.

When evaluating a one-sided limit, you need to be careful when a quantity is approaching zero since its sign is different depending on which way it is approaching zero from. Let us look at some examples.

When evaluating a one-sided limit, you need to be careful when a quantity is approaching zero since its sign is different depending on which way it is approaching zero from. Let us look at some examples.

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