How do minerals change without melting?

Question

Victoria Argento · Accepted Answer

Pseudomorphism!

Cool word isn't it?

This is a really cool way that a mineral can change its atomic structure without melting. But note that the mineral doesn't change its chemical composition in this case.

An example, a mineral such as Kyanite (#"Al"_2"SiO"_5#) has three forms which it can exist in depending on the pressure and temperature conditions.

At low pressure (a few kilobars, roughly a few kilometres into earths crust) andalusite is the stable structure and then at higher temperature moderate pressure sillimanite is the stable structure.

So as we change pressure and temperature a different atomic structure becomes stable and the mineral changes.

Another example is diamond. Diamond is simply carbon (#"C"#) but expose it to pressures of around 40 kilobars or more (> 100 km into the mantle) then you get diamond!

Though, I wouldn't recommend putting your pencil in the oven for a few weeks to try and make diamond! But expose diamond to some high temperature and pressure (below its stability field) and it might just transform back to graphite!

Above is the stability ranges for the three guys I mentioned above, diamond occurs four times higher than this diagram (more than 120km into our mantle)!

NB: #"0.1 GPa " = " 1 kilobar"#

Jonathan Avila · Answer

undefined Minerals can change without melting through processes like recrystallization, metamorphism, and chemical reactions such as hydration, dehydration, and dissolution.