Consider the equilibrium system #CO(g) + Fe_3O_4(s) ⇌ CO_2(g) + 3FeO(s)# How does the equilibrium position shift as a result of each of the following disturbances?
-
Left Right Not CO2 is removed by adding solid NaOH.
-
Left Right Not Additional Fe3O4(s) is added to the system.
-
Left Right Not Dry ice is addded at a constant T.
4 Left Right Not The volume is reduced by one-half at a constant T.
- Left Right Not CO is added.
-
Left Right Not CO2 is removed by adding solid NaOH.
-
Left Right Not Additional Fe3O4(s) is added to the system.
-
Left Right Not Dry ice is addded at a constant T.
4 Left Right Not The volume is reduced by one-half at a constant T.
- Left Right Not CO is added.
- Right
- Not
- Left
- Not
- Right
Applying the principle of Le Chatelier
When the concentration of one of the (gaseous) products falls, the equilibrium moves to the right (to the products).
Changes in volume have no effect on the equilibrium because there are equal numbers of gas molecules on both sides of the reaction (though they do speed up reactions in both directions).
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- Increase in CO concentration: Shifts right
- Increase in CO2 concentration: Shifts left
- Increase in FeO concentration: Shifts left
- Increase in Fe3O4 concentration: Shifts right
- Increase in temperature: Shifts endothermic direction
- Decrease in temperature: Shifts exothermic direction
- Increase in pressure: Shifts to the side with fewer moles
- Decrease in pressure: Shifts to the side with more moles
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When evaluating a one-sided limit, you need to be careful when a quantity is approaching zero since its sign is different depending on which way it is approaching zero from. Let us look at some examples.
When evaluating a one-sided limit, you need to be careful when a quantity is approaching zero since its sign is different depending on which way it is approaching zero from. Let us look at some examples.
When evaluating a one-sided limit, you need to be careful when a quantity is approaching zero since its sign is different depending on which way it is approaching zero from. Let us look at some examples.
When evaluating a one-sided limit, you need to be careful when a quantity is approaching zero since its sign is different depending on which way it is approaching zero from. Let us look at some examples.
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