At a certain temperature, 4.0 mol #NH_3# is introduced into a 2.0 L container, and the #NH_3# partially dissociates to #2NH_3(g)\rightleftharpoonsN_2(g)+3H_2(g)#. At equilibrium, 2.0 mol #NH_3# remains. What is the value of #K_c#?

A clearer version:

At a certain temperature, 4.0 mol #NH_3# is introduced into a 2.0 L container, and the #NH_3# partially dissociates to #2NH_3(g)\rightleftharpoonsN_2(g)+3H_2(g)#.

At equilibrium, 2.0 mol #NH_3# remains. What is the value of #K_c#?

Note: I started an ICE table but I don't know what to put in the #N_2# and #3H_2# columns.

Answer 1
Remember to include the coefficients in the change in concentratio, as well as the exponents. I get #K_c = 1.69#.
If #K_p = K_c(RT)^(Deltan_"gas")#, what would #K_p# be if this reaction has been occurring at #"298 K"#? #R = "0.08206 L"cdot"atm/mol"cdot"K"#. Highlight below to see.
#color(white)("From the reaction, "Deltan_"gas" = (1+3) - (2) = 2,)# #color(white)("since there are 3 mols H"_2, "1 mol N"_2, "and 2 mols NH"_3.)#
#color(white)("So,")#
#color(white)(K_p = 1.69 cdot ("0.08206 L"cdot"atm/mol"cdot"K" cdot "298 K")^((1+3)-(2)))#
#color(white)(~~ 1010" in implied units of atm")#
Let's first find the concentrations, because #K_c# is in terms of concentrations.
#"4.0 mols NH"_3/("2.0 L") = "2.0 M"#
#"2.0 mols NH"_3/("2.0 L") = "1.0 M"#
The ICE table uses #"NH"_3# having the initial concentration of #"2.0 M"# and final of #"1.0 M"#. Therefore, we should be able to find #x# already, but let's assume we don't know #x# yet.
#color(red)(2)"NH"_3(g) rightleftharpoons "N"_2(g) + color(red)(3)"H"_2(g)#
#"I"" "2.0" "" "" "" "0" "" "" "0# #"C"" "-color(red)(2)x" "" "+x" "" "+color(red)(3)x# #"E"" "2.0-color(red)(2)x" "" "x" "" "color(red)(3)x#

Recall that the exponents and concentration change with the coefficients.

Now, the #K_c# would be:
#K_c = (x(color(red)(3)x)^color(red)(3))/(2.0 - color(red)(2)x)^color(red)(2)#
#= (27x^4)/(2.0 - 2x)^2#
But like mentioned, we know #x#. This is because
#2.0 - 2x = "1.0 M"#.

Consequently:

#x = "0.5 M"#.

Consequently,

#color(blue)(K_c) = (27(0.5)^4)/(2.0 - 2(0.5))^2#
#= color(blue)(1.69)#
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Answer 2

The equilibrium constant ( K_c ) is equal to 1.5.

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Answer from HIX Tutor

When evaluating a one-sided limit, you need to be careful when a quantity is approaching zero since its sign is different depending on which way it is approaching zero from. Let us look at some examples.

When evaluating a one-sided limit, you need to be careful when a quantity is approaching zero since its sign is different depending on which way it is approaching zero from. Let us look at some examples.

When evaluating a one-sided limit, you need to be careful when a quantity is approaching zero since its sign is different depending on which way it is approaching zero from. Let us look at some examples.

When evaluating a one-sided limit, you need to be careful when a quantity is approaching zero since its sign is different depending on which way it is approaching zero from. Let us look at some examples.

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