Acetylene is used in blow torches, and burns according to the following equation: 2 C2H2(g) + 5 O2(g) → 4 CO2(g) + 2 H2O(g) Use the following information to calculate the heat of reaction:?
Acetylene is used in blow torches, and burns according to the following
equation:
2 C2H2(g) + 5 O2(g) → 4 CO2(g) + 2 H2O(g)
Use the following information to calculate the heat of reaction:
Hfo
(H2O(g))= -241.82 kJ/mol
Hfo
(CO2(g))= -393.5 kJ/mol
Hfo
(C2H2(g))=226.77 kJ/mol
Acetylene is used in blow torches, and burns according to the following
equation:
2 C2H2(g) + 5 O2(g) → 4 CO2(g) + 2 H2O(g)
Use the following information to calculate the heat of reaction:
Hfo
(H2O(g))= -241.82 kJ/mol
Hfo
(CO2(g))= -393.5 kJ/mol
Hfo
(C2H2(g))=226.77 kJ/mol
Hess' Law states that the overall enthalpy change of a reaction is independent of the route taken.
Thermodynamics is concerned with initial and final states and the law is a consequence of the conservation of energy.
You can solve this problem by constructing a Hess Cycle.
Write down the reaction you are interested in. Below this write down the elements from which the reactants and products are made.
Then complete the cycle as shown:
Notice I have multiplied the
In energy terms the
So we can write:
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To calculate the heat of reaction ((ΔH)), we need to use the standard enthalpies of formation for the substances involved in the reaction. The standard enthalpy of formation for a substance is the change in enthalpy when one mole of the substance is formed from its elements in their standard states.
Given:
- Standard enthalpy of formation of CO₂ = -393.5 kJ/mol
- Standard enthalpy of formation of H₂O = -241.8 kJ/mol
- Standard enthalpy of formation of C₂H₂ = 226.7 kJ/mol
Using the given equation:
2 C₂H₂(g) + 5 O₂(g) → 4 CO₂(g) + 2 H₂O(g)
The heat of reaction ((ΔH)) can be calculated as:
[ΔH = \sumΔH_{\text{products}} - \sumΔH_{\text{reactants}}]
[ΔH = [4(-393.5) + 2(-241.8)] - [2(226.7) + 5(0)]]
[ΔH = [-1574 - 483.6] - [453.4]]
[ΔH = -2057.6 - 453.4]
[ΔH = -2511 , \text{kJ/mol}]
Therefore, the heat of reaction for the combustion of acetylene is -2511 kJ/mol.
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When evaluating a one-sided limit, you need to be careful when a quantity is approaching zero since its sign is different depending on which way it is approaching zero from. Let us look at some examples.
When evaluating a one-sided limit, you need to be careful when a quantity is approaching zero since its sign is different depending on which way it is approaching zero from. Let us look at some examples.
When evaluating a one-sided limit, you need to be careful when a quantity is approaching zero since its sign is different depending on which way it is approaching zero from. Let us look at some examples.
When evaluating a one-sided limit, you need to be careful when a quantity is approaching zero since its sign is different depending on which way it is approaching zero from. Let us look at some examples.
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