10 #cm^3# of carbon monoxide and 10 #cm^3# of oxygen are mixed. What will be the total volume of gas present, in #cm^3#, after the reaction?

They are mixed and the volume is measured at the same temperature and pressure.

#2CO + O_2 -> 2CO_2#

a. 10
b. 15
c. 20
d. 25

The answer given is b. 15, why?

Answer 1

The volume of gas will indeed be equal to #"15 cm"^3#.

This one can be a little tricky, and I'll explain why.

It's crucial to understand that in reactions involving gases maintained at constant pressure and temperature, the mole ratios between the species involved in the reaction equal the volume ratio.

Examine the balanced chemical equation associated with your reaction.

#color(red)(2)"CO"_text((g]) + "O"_text(2(g]) -> color(blue)(2)"CO"_text(2(g])#
Notice that you have a #color(red)(2):1# mole ratio between carbon monoxide and oxygen gas. This tells you that the reaction will always consume twice as many moles o carbon monoxide than of oxygen gas.

However, since the pressure and temperature of the gases we work with are the same, you can say the same thing about their volumes.

Stated differently, the amount of carbon monoxide that is consumed by the reaction is always twice that of the oxygen gas.

Now, here's where the tricky part comes in. Notice that the problem provides you with equal volumes of #"CO"# and #"O"_2#.
This is a problem because you know that you'd need a volume of #"CO"# that is twice as large as the volume of #"O"_2#.

This leads you to the conclusion that you are working with a limiting reagent; in particular, carbon monoxide will do so because it will be used up before all of the oxygen has a chance to react.

Thus, it can be said that the response will only use

#10color(red)(cancel(color(black)("cm"^3"CO"))) * ("1 cm"^3"O"_2)/(color(red)(2)color(red)(cancel(color(black)("cm"^3"CO")))) = "5 cm"^3color(white)(a)"O"_2#
So, #"10 cm"^3# of #"CO"# wil lreact with #"5 cm"^3# of #"O"_2#, leaving #"5 cm"^3# of #"O"_2# in excess.
Now look at the #color(red)(2):color(blue)(2)# volume ratio that exists between #"CO"# and #"CO"_2#. This tells you that for a given volume of #"CO"# that takes part in the reaction, the reaction produces an equal volume of #"CO"_2#.
So, if #"10 cm"^3# of #"CO"# react, you will get #"10 cm"^3# of #"CO"_2# produced.

This implies that following the completion of the reaction, the reaction vessel will contain

#V_"gas" = overbrace(V_(O_2))^(color(purple)("in excess")) + overbrace(V_(CO_2))^(color(brown)("produced"))#
#V_"gas" = "5 cm"^3 + "1 0cm"^3 = color(green)("15 cm"^3)#
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Answer 2

According to the reaction equation (2CO + O_2 \rightarrow 2CO_2), for every 2 volumes of carbon monoxide (CO) and 1 volume of oxygen ((O_2)) consumed, 2 volumes of carbon dioxide ((CO_2)) are produced.

Given that 10 cm^3 of carbon monoxide and 10 cm^3 of oxygen are mixed, the total volume of gas present before the reaction is 20 cm^3.

After the reaction, all the carbon monoxide and oxygen will react to form carbon dioxide. Since the reaction consumes equal volumes of CO and (O_2), and the ratio of CO to (O_2) is 2:1, all of both gases will react fully. Therefore, the total volume of gas after the reaction will still be 20 cm^3.

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Answer from HIX Tutor

When evaluating a one-sided limit, you need to be careful when a quantity is approaching zero since its sign is different depending on which way it is approaching zero from. Let us look at some examples.

When evaluating a one-sided limit, you need to be careful when a quantity is approaching zero since its sign is different depending on which way it is approaching zero from. Let us look at some examples.

When evaluating a one-sided limit, you need to be careful when a quantity is approaching zero since its sign is different depending on which way it is approaching zero from. Let us look at some examples.

When evaluating a one-sided limit, you need to be careful when a quantity is approaching zero since its sign is different depending on which way it is approaching zero from. Let us look at some examples.

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